Electrochemical dilatometer ECD-3

Test cell for the measurement of electrode strain (thickness change) in aprotic as well as aqueous electrolytes

Electrochemical dilatometer ECD-3

Test cell for the measurement of electrode strain (thickness change) in aprotic as well as aqueous electrolytes

Electrochemical dilatometer ECD-3

Test cell for the measurement of electrode strain (thickness change) in aprotic as well as aqueous electrolytes

Product overview

Watch your electrodes breathing

The ECD-3 is a research grade instrument dedicated to the measurement of charge-induced strain (expansion and shrinkage) of electrodes down to the sub-micrometer range. The ECD-3 is particularly developed for the investigation of Li-ion battery and other insertion-type electrodes. It may be used in organic as well as aqueous electrolyte solutions.

The ECD-3 is the result of more than 10 years experience in this field. The heart of the ECD-3 is an electrochemical cell, which is hermetically tight against ambient atmosphere. The two electrodes inside are separated by a stiff glass frit, which is fixed in position. The upper (working) electrode is sealed through a thin metal membrane, which transmits any charge-induced height change to the sensor/load unit on the top.

A high-resolution displacement transducer detects dimensional changes ranging from 20 nanometers up to 500 micrometers during an experiments, which can take between a few seconds and many days. A simple weight serves to adjust the load on the working electrode. The potential of the working electrode can either be controlled against the counter electrode (cell voltage control) or against an additional reference electrode.

Improvements of the ECD-3 (in comparison to previous versions)

  • Elimination of tubing and external valves reduces the risk of leakage and saves effort.

  • Use of special polymer with minimal water absorption reduces drying effort and accelerates work flow.

  • Use of a smaller glass frit reduces amount of electrolyte required (approx. 0.5 cm³)

  • Better handling saves time and effort.

Specifications

Height230 mm
Width100 mm
Depth110 mm
Weightapprox. 1.5 kg
Displacement sensor systemLVDT
Displacement range500 µm
Displacement resolution≤ 50 nm
Signal drift (sample-free)≤ 100 nm / hour
Test specimenElectrode films, optional single crystals / grains Diameter ≤ 10 mm, thickness ≤ 1 mm
Load on test specimenapprox. 1 N
Chemical compatibilityAprotic organic electrolytes; optional aqueous electrolytes
Cell electrolyte volumeapprox. 0.5 ml

Specifications

ECD-3 User Manual
Release1.32
TypePDF
Size3.3 MB
Download

Part Kit for Testing Single Crystals/Grains with the ECD-3 and ECD-3-nano User Manual
Release2.01
TypePDF
Size0,6 MB
Download

Delivery scope

 

#ComponentOrder no.
1ECD-3 dilatometer
2Box ECD-3ECE1-00-0006-E
3ECD sensor cableECE1-00-0036-A
4ECD-3 cell cableECE1-00-0033-F
5Power supply 15W/24V DCELT9045
6Power supply adapterELT9078
7USB cable typ A/B (2.0 m)ELT9167
Accessories kit:
8O-Ring 33.05 mm x 1.78 mm (2 pcs.)DIC9034
9PE-Seal for ECD (33.3 x 1.6),(2 pcs.)ECC1-01-0043-B
10Ferrule 1.0 (2 pcs.)ECC1-00-0029-B
11Ferrule 1.5 (2 pcs.)ECC1-00-0029-C
12O-Ring 50.5 mm x 1.78 mm (2 pcs.)DIC9038
13Membrane (aprotic) 1.4404ECC1-00-0019-D
14Spacer disc (set) 2.1 - 2.3ECC1-01-0012-F
15Demonstration kit (5 x activated carbon electrode foil with 5% PTFE Binder, 10 mm)ECD1-00-0900-A
16Filling tube with syringeECD3-01-0001-A
17 CD containing EC-Link data logger software ECE1-00-0052-A
18TweezersWZG9001
19Spherical allen screw driver 3 mmWZG9002
20Allen screw driver 2.5 mmWZG9003
21Vacuum tweezersWZG9004
22Set allen wrenchECC1-01-0028-A

Upgrade kits for typical configurations

In the standard configuration, the ECD-3 is equipped for aprotic electrochemistry (dilatometer cell, sensor and sensor-controller with dc-voltage output -10 to 10 V) with integrated USB data logger. Materials in media contact are stainless steel and PEEK. The user has to provide all peripheral equipment like temperature chamber and potentiostat.

Various add-ons are available for special testing requirements:

Upgrade Kit Aqueous: replaces stainless steel parts by gold parts and thus makes the ECD-3 compatible with aqueous electrochemistry.

ECD-3 Full Cell Kit: Part kit for testing full cells without T-frit.

Part Kit for Testing Single Crystals/Grains: Part kit for using single grains or crystals instead of bound electrode films.

Consumables

Cell Body: Cell Body: Cell Body:
T-Frit 10/12.5Glass window (5 pieces)ECC1-00-0041-B
Membrane (aprotic) 1.4404Membrane (aprotic) 1.4404ECC1-00-0019-D
O-Ring 33.05 x 1.78 mmO-Ring 33.05 x 1.78 mmDIC9034
O-Ring 50.5 x 1.78 mm O-Ring 50.5 x 1.78 mm DIC9038
Ferrule 1.0Ferrule 1.0ECC1-00-0029-B
Ferrule 1.5 Ferrule 1.5 ECC1-00-0029-C
PE-Seal for ECD (33 x 1.6)PE-Seal for ECD (33 x 1.6)ECC1-01-0043-B
PE-seal for ECD-3 pistonPE-seal for ECD-3 pistonECC1-01-0044-B
Spacer disc (set) 2.1-2.3Spacer disc (set) 2.1-2.3ECC1-01-0012-F
Spacer disc (set) 1.8-2.0Spacer disc (set) 1.8-2.0ECC1-01-0012-G
Spacer disc (set) 1.5-1.7Spacer disc (set) 1.5-1.7ECC1-01-0012-H
Spacer disc (set) 1.2-1.4Spacer disc (set) 1.2-1.4ECC1-01-0012-K
Spacer disc (set) 0.9-1.1Spacer disc (set) 0.9-1.1ECC1-01-0012-L
Sensor Unit:Sensor Unit: Sensor Unit:
Socket screwSocket screwDIN-912 M4 x 12

Spare parts

Sensor unit

Cell Body

Shut-off valve

Central CE piston

Spring load

REF electrode ECD, long

Product overview

Watch your electrodes breathing

The ECD-3 is a research grade instrument dedicated to the measurement of charge-induced strain (expansion and shrinkage) of electrodes down to the sub-micrometer range. It is particularly developed for the investigation of Li-ion battery and other insertion-type electrodes. It may be used in organic as well as aqueous electrolyte solutions.

The ECD-3 is the result of more than 10 years experience in this field. The heart of the ECD-3 is an electrochemical cell, which is hermetically tight against ambient atmosphere. The two electrodes inside are separated by a stiff glass frit, which is fixed in position. The upper (working) electrode is sealed through a thin metal membrane, which transmits any charge-induced height change to the sensor/load unit on the top.

A high-resolution displacement transducer detects dimensional changes ranging from 20 nanometers up to 500 micrometers during an experiments, which can take between a few seconds and many days. A simple weight serves to adjust the load on the working electrode. The potential of the working electrode can either be controlled against the counter electrode (cell voltage control) or against an additional reference electrode.

Improvements of the ECD-3 (in comparison to previous versions)

  • Elimination of tubing and external valves reduces the risk of leakage and saves effort.

  • Use of special polymer with minimal water absorption reduces drying effort and accelerates work flow.

  • Use of a smaller glass frit reduces amount of electrolyte required (approx. 0.5 cm³)

  • Better handling saves time and effort.

Specifications

Height230 mm
Width100 mm
Depth110 mm
Weightapprox. 1.5 kg
Displacement sensor systemLVDT
Displacement range500 µm
Displacement resolution≤ 50 nm
Signal drift (sample-free)≤ 100 nm / hour
Test specimenElectrode films, optional single crystals / grains Diameter ≤ 10 mm, thickness ≤ 1 mm
Load on test specimenapprox. 1 N
Chemical compatibilityAprotic organic electrolytes; optional aqueous electrolytes
Cell electrolyte volumeapprox. 0.5 ml

Specifications

ECD-3 User Manual
Release1.32
TypePDF
Size3.3 MB
Download

Part Kit for Testing Single Crystals/Grains with the ECD-3 and ECD-3-nano User Manual
Release2.01
TypePDF
Size0,6 MB
Download

Delivery scope

 

#ComponentOrder no.
1ECD-3 dilatometer
2Box ECD-3ECE1-00-0006-E
3ECD sensor cableECE1-00-0036-A
4ECD-3 cell cableECE1-00-0033-F
5Power supply 15W/24V DCELT9045
6Power supply adapterELT9078
7USB cable typ A/B (2.0 m)ELT9167
Accessories kit:
8O-Ring 33.05 mm x 1.78 mm (2 pcs.)DIC9034
9PE-Seal for ECD (33.3 x 1.6),(2 pcs.)ECC1-01-0043-B
10Ferrule 1.0 (2 pcs.)ECC1-00-0029-B
11Ferrule 1.5 (2 pcs.)ECC1-00-0029-C
12O-Ring 50.5 mm x 1.78 mm (2 pcs.)DIC9038
13Membrane (aprotic) 1.4404ECC1-00-0019-D
14Spacer disc (set) 2.1 - 2.3ECC1-01-0012-F
15Demonstration kit (5 x activated carbon electrode foil with 5% PTFE Binder, 10 mm)ECD1-00-0900-A
16Filling tube with syringeECD3-01-0001-A
17 CD containing EC-Link data logger software ECE1-00-0052-A
18TweezersWZG9001
19Spherical allen screw driver 3 mmWZG9002
20Allen screw driver 2.5 mmWZG9003
21Vacuum tweezersWZG9004
22Set allen wrenchECC1-01-0028-A

Upgrade kits for typical configurations

In the standard configuration, the ECD-3 is equipped for aprotic electrochemistry (dilatometer cell, sensor and sensor-controller with dc-voltage output -10 to 10 V) with integrated USB data logger. Materials in media contact are stainless steel and PEEK. The user has to provide all peripheral equipment like temperature chamber and potentiostat.

Various add-ons are available for special testing requirements:

Upgrade Kit Aqueous: replaces stainless steel parts by gold parts and thus makes the ECD-3 compatible with aqueous electrochemistry.

ECD-3 Full Cell Kit: Part kit for testing full cells without T-frit.

Part Kit for Testing Single Crystals/Grains: Part kit for using single grains or crystals instead of bound electrode films.

Consumables

Cell Body: Cell Body: Cell Body:
T-Frit 10/12.5Glass window (5 pieces)ECC1-00-0041-B
Membrane (aprotic) 1.4404Membrane (aprotic) 1.4404ECC1-00-0019-D
O-Ring 33.05 x 1.78 mmO-Ring 33.05 x 1.78 mmDIC9034
O-Ring 50.5 x 1.78 mm O-Ring 50.5 x 1.78 mm DIC9038
Ferrule 1.0Ferrule 1.0ECC1-00-0029-B
Ferrule 1.5 Ferrule 1.5 ECC1-00-0029-C
PE-Seal for ECD (33 x 1.6)PE-Seal for ECD (33 x 1.6)ECC1-01-0043-B
PE-seal for ECD-3 pistonPE-seal for ECD-3 pistonECC1-01-0044-B
Spacer disc (set) 2.1-2.3Spacer disc (set) 2.1-2.3ECC1-01-0012-F
Spacer disc (set) 1.8-2.0Spacer disc (set) 1.8-2.0ECC1-01-0012-G
Spacer disc (set) 1.5-1.7Spacer disc (set) 1.5-1.7ECC1-01-0012-H
Spacer disc (set) 1.2-1.4Spacer disc (set) 1.2-1.4ECC1-01-0012-K
Spacer disc (set) 0.9-1.1Spacer disc (set) 0.9-1.1ECC1-01-0012-L
Sensor Unit:Sensor Unit: Sensor Unit:
Socket screwSocket screwDIN-912 M4 x 12

Spare parts

Sensor unit

Cell Body

Shut-off valve

Central CE piston

Spring load

REF electrode ECD, long

Watch your electrodes breathing

The ECD-3 is a research grade instrument dedicated to the measurement of charge-induced strain (expansion and shrinkage) of electrodes down to the sub-micrometer range. It is particularly developed for the investigation of Li-ion battery and other insertion-type electrodes. It may be used in organic as well as aqueous electrolyte solutions.
The ECD-3 is the result of more than 10 years experience in this field. The heart of the ECD-3 is an electrochemical cell, which is hermetically tight against ambient atmosphere. The two electrodes inside are separated by a stiff glass frit, which is fixed in position. The upper (working) electrode is sealed through a thin metal membrane, which transmits any charge-induced height change to the sensor/load unit on the top.

A high-resolution displacement transducer detects dimensional changes ranging from 20 nanometers up to 500 micrometers during an experiments, which can take between a few seconds and many days. A simple weight serves to adjust the load on the working electrode. The potential of the working electrode can either be controlled against the counter electrode (cell voltage control) or against an additional reference electrode.

Improvements of the ECD-3 (in comparison to previous versions)

  • Elimination of tubing and external valves reduces the risk of leakage and saves effort.

  • Use of special polymer with minimal water absorption reduces drying effort and accelerates work flow.

  • Use of a smaller glass frit reduces amount of electrolyte required (approx. 0.5 cm³)

  • Better handling saves time and effort.

ECD-3 overview

Specifications
Height230 mm
Width100 mm
Depth110 mm
Weightapprox. 1.5 kg
Displacement sensor systemLVDT
Displacement range500 µm
Displacement resolution≤ 50 nm
Signal drift (sample-free)≤ 100 nm / hour
Test specimenElectrode films, optional single crystals / grains Diameter ≤ 10 mm, thickness ≤ 1 mm
Load on test specimenapprox. 1 N
Chemical compatibilityAprotic organic electrolytes; optional aqueous electrolytes
Cell electrolyte volumeapprox. 0.5 ml
Manuals
ECD-3 User Manual
Release1.32
TypePDF
Size3.3 MB
Download
Part Kit for Testing Single Crystals/Grains with the ECD-3 and ECD-3-nano User Manual
Release2.01
TypePDF
Size0,6 MB
Download
Delivery scope
#ComponentOrder no.
1ECD-3 dilatometer
2Box ECD-3ECE1-00-0006-E
3ECD sensor cableECE1-00-0036-A
4ECD-3 cell cableECE1-00-0033-F
5Power supply 15W/24V DCELT9045
6Power supply adapterELT9078
7USB cable typ A/B (2.0 m)ELT9167
Accessories kit:
8O-Ring 33.05 mm x 1.78 mm (2 pcs.)DIC9034
9PE-Seal for ECD (33.3 x 1.6),(2 pcs.)ECC1-01-0043-B
10Ferrule 1.0 (2 pcs.)ECC1-00-0029-B
11Ferrule 1.5 (2 pcs.)ECC1-00-0029-C
12O-Ring 50.5 mm x 1.78 mm (2 pcs.)DIC9038
13Membrane (aprotic) 1.4404ECC1-00-0019-D
14Spacer disc (set) 2.1 - 2.3ECC1-01-0012-F
15Demonstration kit (5 x activated carbon electrode foil with 5% PTFE Binder, 10 mm)ECD1-00-0900-A
16Filling tube with syringeECD3-01-0001-A
17 CD containing EC-Link data logger software ECE1-00-0052-A
18TweezersWZG9001
19Spherical allen screw driver 3 mmWZG9002
20Allen screw driver 2.5 mmWZG9003
21Vacuum tweezersWZG9004
22Set allen wrenchECC1-01-0028-A

 

Upgrade Kits

In the standard configuration, the ECD-3 is equipped for aprotic electrochemistry (dilatometer cell, sensor and sensor-controller with dc-voltage output -10 to 10 V) with integrated USB data logger. Materials in media contact are stainless steel and PEEK. The user has to provide all peripheral equipment like temperature chamber and potentiostat.

Various add-ons are available for special testing requirements:

Upgrade Kit Aqueous: replaces stainless steel parts by gold parts and thus makes the ECD-3 compatible with aqueous electrochemistry.

ECD-3 Full Cell Kit: Part kit for testing full cells without T-frit.

Part Kit for Testing Single Crystals/Grains: Part kit for using single grains or crystals instead of bound electrode films.

Consumables
Cell Body: Cell Body: Cell Body:
T-Frit 10/12.5Glass window (5 pieces)ECC1-00-0041-B
Membrane (aprotic) 1.4404Membrane (aprotic) 1.4404ECC1-00-0019-D
O-Ring 33.05 x 1.78 mmO-Ring 33.05 x 1.78 mmDIC9034
O-Ring 50.5 x 1.78 mm O-Ring 50.5 x 1.78 mm DIC9038
Ferrule 1.0Ferrule 1.0ECC1-00-0029-B
Ferrule 1.5 Ferrule 1.5 ECC1-00-0029-C
PE-Seal for ECD (33 x 1.6)PE-Seal for ECD (33 x 1.6)ECC1-01-0043-B
PE-seal for ECD-3 pistonPE-seal for ECD-3 pistonECC1-01-0044-B
Spacer disc (set) 2.1-2.3Spacer disc (set) 2.1-2.3ECC1-01-0012-F
Spacer disc (set) 1.8-2.0Spacer disc (set) 1.8-2.0ECC1-01-0012-G
Spacer disc (set) 1.5-1.7Spacer disc (set) 1.5-1.7ECC1-01-0012-H
Spacer disc (set) 1.2-1.4Spacer disc (set) 1.2-1.4ECC1-01-0012-K
Spacer disc (set) 0.9-1.1Spacer disc (set) 0.9-1.1ECC1-01-0012-L
Sensor Unit:Sensor Unit: Sensor Unit:
Socket screwSocket screwDIN-912 M4 x 12
Spare parts

Sensor unit

Cell Body

Shut-off valve

Central CE piston

Spring load

REF electrode ECD, long

Gallery

Sample test results

Expanding and shrinking of a graphite electrode during lithium insertion and extraction (figure left). The detailed view on the right shows the onset of expansion at 1.9V vs. Li / Li+ (figure right).Expanding and shrinking of a graphite electrode during lithium insertion and extraction (figure left). The detailed view on the right shows the onset of expansion at 1.9V vs. Li / Li+ (figure right).
Current response and height change of layered ruthenium oxide HRO in 2 M H2SO4 during slow scan voltammetry. Courtesy of Prof. Wataru Sugimoto, Shinshu University, Japan.Current response and height change of layered ruthenium oxide HRO in 2 M H2SO4 during slow scan voltammetry. Courtesy of Prof. Wataru Sugimoto, Shinshu University, Japan.

Videos

Assembly of the ECD-3-nano electrochemical dilatometer

In this video, you will learn how to assemble an ECD-3 electrochemical dilatometer inside the glove box, how to connect it and finally how to adjust the sensor for testing.

ResolutionDateTypeSize
1920x1080px09/2016wmv745 MBDownload
1280x720px09/2016wmv460 MBDownload

Watch and download more of our videos on our video page.

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